BINAP)]Cl
(R)-RuCl[(p-cymene)(DM-BINAP)]Cl Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl
CAS: 944451-24-5
Molecular Formula: C62H60Cl2P2Ru
BINAP)]Cl - Names and Identifiers
BINAP)]Cl - Physico-chemical Properties
| Molecular Formula | C62H60Cl2P2Ru |
| Molar Mass | 1039.08 |
| Melting Point | >100°C |
| Appearance | Powder |
| Color | orange to brown |
| Storage Condition | 2-8°C |
| Sensitive | air sensitive |
BINAP)]Cl - Risk and Safety
| WGK Germany | 3 |
BINAP)]Cl - Introduction
(R)-RuCl[(p-cymene)(DM-BINAP)]Cl Chloro{(R)-( )-2,2 '-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl, also known as (R)-RuCl[(p-cymene)(DM-BINAP)]Cl or rhodium (II) chloride [RuCl(p-cymene)((R)-xylbinap)]Cl, is an organometallic compound. The following is a description of the properties, uses, preparation and safety information of the compound:
Nature:
-Appearance: It is a solid with brownish red to reddish brown crystals.
-Solubility: Soluble in common organic solvents (such as dimethylformamide, dichloromethane), insoluble in water.
-Melting point: about 120-125 degrees Celsius.
-Stability: It is stable in an inert gas environment, but may be decomposed by the influence of moisture and oxygen in the air.
Use:
-As a catalyst: Because it contains ruthenium and phosphine ligands, it is often used as a catalyst, especially in asymmetric synthesis reactions, such as catalytic asymmetric hydrogenation, asymmetric cycloaddition, etc.
Preparation Method:
-The compound can be prepared by the method of synthetic metal organic chemistry. Typically, the chloride intermediate is formed by reaction in the presence of RuCl(p-cymene)Cl2 and (R)-( )-2,2 '-bis (di-(3,5-xylenyl) phosphino)-1,1'-binaphthyl (DM-BINAP), which is then further processed to give the desired product.
Safety Information:
-This is an organometallic compound that is potentially dangerous and toxic. During operation or use, it is necessary to follow appropriate safety procedures, including wearing appropriate protective equipment (such as gloves, glasses and laboratory coats).
-It should be operated in a well-ventilated area to avoid inhalation of vapor or dust.
-The contact and usage of this compound should be strictly controlled to avoid skin contact and inhalation.
-Waste Disposal: Waste shall be disposed of or recycled safely in accordance with local laws and regulations.
Nature:
-Appearance: It is a solid with brownish red to reddish brown crystals.
-Solubility: Soluble in common organic solvents (such as dimethylformamide, dichloromethane), insoluble in water.
-Melting point: about 120-125 degrees Celsius.
-Stability: It is stable in an inert gas environment, but may be decomposed by the influence of moisture and oxygen in the air.
Use:
-As a catalyst: Because it contains ruthenium and phosphine ligands, it is often used as a catalyst, especially in asymmetric synthesis reactions, such as catalytic asymmetric hydrogenation, asymmetric cycloaddition, etc.
Preparation Method:
-The compound can be prepared by the method of synthetic metal organic chemistry. Typically, the chloride intermediate is formed by reaction in the presence of RuCl(p-cymene)Cl2 and (R)-( )-2,2 '-bis (di-(3,5-xylenyl) phosphino)-1,1'-binaphthyl (DM-BINAP), which is then further processed to give the desired product.
Safety Information:
-This is an organometallic compound that is potentially dangerous and toxic. During operation or use, it is necessary to follow appropriate safety procedures, including wearing appropriate protective equipment (such as gloves, glasses and laboratory coats).
-It should be operated in a well-ventilated area to avoid inhalation of vapor or dust.
-The contact and usage of this compound should be strictly controlled to avoid skin contact and inhalation.
-Waste Disposal: Waste shall be disposed of or recycled safely in accordance with local laws and regulations.
Last Update：2024-04-09 21:04:16
![BINAP)]Cl](http://res.chembk.com/assets/images/structure/944451-24-5.gif)
Supplier List
Spot supply
Product Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride Request for quotationCAS: 944451-24-5
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365
Wechat: 18916960931
Spot supply
Product Name: [RuCl(p-cymene)((R)-xylbinap)]Cl Visit Supplier Webpage Request for quotationCAS: 944451-24-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride Visit Supplier Webpage Request for quotationCAS: 944451-24-5
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Product Name: Chloro[(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride Visit Supplier Webpage Request for quotation
CAS: 944451-24-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
CAS: 944451-24-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Spot supply
Product Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride Request for quotationCAS: 944451-24-5
Tel: 400-968-2212
Email: 3623107365@qq.com
Mobile: 18916960931
QQ: 3623107365
Wechat: 18916960931
Spot supply
Product Name: [RuCl(p-cymene)((R)-xylbinap)]Cl Visit Supplier Webpage Request for quotationCAS: 944451-24-5
Tel: +86-18821248368
Email: Int06@meryer.com
Mobile: +86-18821248368
QQ: 495145328
WhatsApp: +86-18821248368
Spot supply
Product Name: Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride Visit Supplier Webpage Request for quotationCAS: 944451-24-5
Tel: +86-400-900-4166
Email: product@acmec-e.com
Mobile: +86-18621343501
QQ: 2881950922
Wechat: 18621343501
WhatsApp: +86-18621343501
Product Name: Chloro[(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride Visit Supplier Webpage Request for quotation
CAS: 944451-24-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
CAS: 944451-24-5
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
View History